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DIETHYLALUMINUM CHLORIDE

CAS No.
96-10-6
Chemical Name:
DIETHYLALUMINUM CHLORIDE
Synonyms
DEAC;DIETHYLALUMINIUM CHLORIDE;Diethylaluminum;uminum chL;Diethylchoroaluminum;CHLORODIETHYLALUMINUM;chlorodiethyl-aluminu;Diethylchloroaluminum;Et2AlCl 1M in heptane;chloro(diethyl)alumane
CBNumber:
CB9783672
Molecular Formula:
C4H10AlCl
Molecular Weight:
120.56
MDL Number:
MFCD00000459
MOL File:
96-10-6.mol
MSDS File:
SDS
Last updated:2024-10-21 15:54:43

DIETHYLALUMINUM CHLORIDE Properties

Melting point -85°C
Boiling point 125°C 50mm
Density 0.887 g/mL at 25 °C
vapor pressure 3 mmHg ( 60 °C)
Flash point −9 °F
storage temp. 0-6°C
solubility Miscible with hexane.
form Solution
Specific Gravity 0.711 (20/4℃)
color Colorless
Water Solubility reac H2O [CRC10]
Sensitive Air & Moisture Sensitive
Merck 326
BRN 4123259
CAS DataBase Reference 96-10-6(CAS DataBase Reference)
EWG's Food Scores
FDA UNII
EPA Substance Registry System

SAFETY

Risk and Safety Statements

Symbol(GHS)  trực tiếp đá gà hôm nayLiên kết đăng nhậptrực tiếp đá gà hôm nayLiên kết đăng nhậptrực tiếp đá gà hôm nayLiên kết đăng nhậptrực tiếp đá gà hôm nayLiên kết đăng nhập
GHS02,GHS05,GHS07,GHS08
Signal word  Danger
Hazard statements  H225-H250-H260-H304-H314-H336-H361d-H373-H412
Precautionary statements  P210-P231+P232-P280-P301+P330+P331-P303+P361+P353-P304+P340+P310-P305+P351+P338-P370+P378
Hazard Codes  F,C,N
Risk Statements  14-17-34-67-65-62-51/53-48/20-14/15-11-63-50/53
Safety Statements  36/37/39-45-62-61-43-26-16
RIDADR  UN 3394 4.2/PG 1
WGK Germany  2
RTECS  BD0558000
10
TSCA  Yes
HazardClass  4.3
PackingGroup  I
HS Code  29319090
NFPA 704
4
3 3

DIETHYLALUMINUM CHLORIDE price More Price(15)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 256714 Diethylaluminum chloride 97% 96-10-6 100g $358 2025-03-01 Buy
Sigma-Aldrich 192732 Diethylaluminum chloride solution 25 wt. % in toluene 96-10-6 100g $105.6 2025-03-01 Buy
Sigma-Aldrich 212806 Diethylaluminum chloride solution 1.0?M in hexanes 96-10-6 4X25ML $86.3 2024-06-20 Buy
Sigma-Aldrich 212806 Diethylaluminum chloride solution 1.0?M in hexanes 96-10-6 100ML $90.9 2024-06-20 Buy
Sigma-Aldrich 212806 Diethylaluminum chloride solution 1.0?M in hexanes 96-10-6 800ML $332 2024-06-20 Buy
Product number Packaging Price Buy
256714 100g $358 Buy
192732 100g $105.6 Buy
212806 4X25ML $86.3 Buy
212806 100ML $90.9 Buy
212806 800ML $332 Buy

DIETHYLALUMINUM CHLORIDE Chemical Properties,Uses,Production

Chemical Properties

The aluminum alkyl halides are flammable, reactive, and may be spontaneously combustible in air. They are colorless to yellow liquids. Ethylaluminum dichloride:(563-43-9):

Chemical Properties

colorless solution

Production Methods

Ethylaluminum sesquichloride (26.5 kg) added to a nitrogen-purged reactor, was heated to 175 ℃. Then, while the mixture was stirred vigorously, 1.1 kg sodium was added over a 30 min period; the mixture was further heated at 155 – 190 ℃ for 60 min. The diethylaluminum chloride product distilled from the reactor at 100 – 161 ℃ (1.3 – 6.1 kPa). In this example, an excess of ethylaluminum sesquichloride was employed to facilitate draining the voluminous byproduct salt and aluminum solids from the reactor. In an alternate approach, a heavy hydrocarbon oil, added prior to reaction, may be employed to remove the solids in slurry form, permitting the use of a stoichiometric ratio of ethylaluminum sesquichloride and sodium reactants.

General Description

Colorless liquid. Dangerous fire and explosion hazard. Used as an intermediate in production of organometallics.

Air & Water Reactions

Pyrophoric in air [Hawley]. Reacts violently with water, Rose(1961).

Reactivity Profile

Organometallics, such as DIETHYLALUMINUM CHLORIDE, are reactive with many other groups. Incompatible with acids and bases. Organometallics are good reducing agents and therefore incompatible with oxidizing agents. Often reactive with water to generate toxic or flammable gases. Organometallics containing halogens (fluorine, chlorine, bromine, iodine) bonded to the metal typically with generate ga浏览发动机seous hydrohalic acids (HF, HCl, HBr, HI) with water.

Potential Exposure

These materials are used as components of olefin polymerization catalysts. The reader is referred to the entry on “Aluminum alkyls” for additional information on this entry. The aluminum alkyl halides parallel very closely the aluminum alkyls

Shipping

UN3052 Spontaneously combustible. Water reactive releasing large quantities of toxic and deadly hydrogen gas. (Note: this number does not appear in the 49/CFR HazMat tables)

Purification Methods

Distil it from excess dry NaCl (to remove ethyl aluminium dichloride) in a 50-cm column containing a heated nichrome spiral. [Beilstein 4 IV 4403.]

Incompatibilities

The aluminum alkyl halides are strong reducing agents; they react—possibly violently—with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. These chemicals react violently with nitromethaneEthylaluminum sesquichloride reacts explosively with carbon tetrachloride at room temperature. This chemical reacts violently with water, forming corrosive hydrogen chloride and flammable ethane gas. Diethylaluminum chloride may form an explosive product with chlorine azide.
Global( 128)Suppliers
Supplier Tel Email Country ProdList Advantage
Henan Tianfu Chemical Co.,Ltd.
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View Lastest Price from DIETHYLALUMINUM CHLORIDE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
trực tiếp đá gà hôm nayLiên kết đăng nhập 2024-03-30 Diethylaluminum chloride, 97%
96-10-6
US $50.00 / kg 1kg 99% 20 tons Hebei Duling International Trade Co. LTD
trực tiếp đá gà hôm nayLiên kết đăng nhập 2022-07-13 DIETHYLALUMINUM CHLORIDE
96-10-6
US $15.00-10.00 / KG 1KG 99%+ HPLC Monthly supply of 1 ton Zhuozhou Wenxi import and Export Co., Ltd
trực tiếp đá gà hôm nayLiên kết đăng nhập 2022-07-10 DIETHYLALUMINUM CHLORIDE
96-10-6
US $15.00-10.00 / KG 1KG 99%+ HPLC Monthly supply of 1 ton Zhuozhou Wenxi import and Export Co., Ltd
aluminiumdiethylchloride Aluminum, chlorodiethyl- Diethylchoroaluminum DIETHYLALUMINUM CHLORIDE CHLORODIETHYLALUMINUM Aluminium diethyl monochloride Diethylaluminium chloride, 1M solution in hexanes Diethylaluminumchloride,97% diethylaluminum chloride solution aluminum diethyul monochloride DIETHYLALUMINUM CHLORIDE, 1.0M SOLUTION IN HEPTANE DIETHYLALUMINUM CHLORIDE, 25 WT. % (1.8M ) SOLUTION IN TOLUENE DIETHYLALUMINUM CHLORIDE, 1.0M SOLUTION IN HEXANES DIETHYLALUMINUM CHLORIDE SOLUTION, ~1 M IN HEXANE DIETHYLALUMINUM CHLORIDE STEEL FLASK 0.3 L (NET ~150 G) Diethylaluminumchloride,25%w/winheptane,95+% Diethylaluminium chloride, 0.9M solution in toluene Aluminiumdiethylmonochlorid DiethylaluMinuM chloride, 2.0 M solution in hexanes, J&KSeal DiethylaluMinuM chloride, 0.9 M solution in toluene, J&KSeal DiethylaluMinuM chloride, 1.0 M solution in hexanes, J&KSeal DiethylaluMinuM chloride, 0.9 M solution in Toluene, SpcSeal DiethylaluMinuM chloride, 1.0 M solution in Hexanes, SpcSeal DiethylaluMinuM chloride, 2.0 M solution in hexanes, SpcSeal Aluminum,chlorodiethyl- aluminumdiethylmonochloride Chloro(diethyl)aluminium chlorodiethyl-aluminu dichlorotetraethyldi-aluminu Diethylaluminum monochloride diethylaluminummonochloride Diethylchloroaluminum Diethylaluminum Chloride (ca. 15% in Hexane, ca. 0.87mol/L) Chlorodiethylaluminum: (Diethylaluminum chloride) Diethylaluminium chloride, 1.1M solution in toluene Diethylaluminium chloride1.1M solution in tolueneAcroSeal§3 Diethylaluminium chloride1M solution in hexanesAcroSeal§3 Diethylaluminium chloride0.9M solution in tolueneAcroSeal§3 DIETHYLALMINIUMCHLORIDE Diethylaluminum chloride, 96%, 25% w/w in heptane Diethylaluminum Chloride, 20% Solution in Hexanes Diethylaluminum chloride solution 1.0 in heptane Diethylaluminum chloride solution 25t. % in toluene Diethylaluminum chloride 97% Diethylaluminium chloride, 0.9M solution in toluene, AcroSeal Diethylaluminium chloride, 1.1M solution in toluene, AcroSeal Diethylaluminium chloride, 1M solution in hexanes, AcroSeal Diethylaluminum chloride, 97% (Material solid in non-returnable cylinder) Diethylaluminum Chloride, 25% in Toluene uminum chL DIETHYLALUMINUM CHLORIDE ISO 9001:2015 REACH Et2AlCl 1M in heptane Diethylaluminum Chloride - 25% in Toluene (about 2M) Diethylaluminum Chloride Solution (1M in hexanes) chloro(diethyl)alumane DEAC DIETHYLALUMINIUM CHLORIDE Diethylaluminum
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